Alkalinity is what we use to measure bicarbonate as test kits for bicarbonate would be difficult and expensive to obtain. Alkalinity in (very) short is salt water’s ability to buffer the pH against acids which try to lower the pH. Generally, natural seawater contains an alkalinity level of 7 dKH. Corals use calcium and alkalinity in equal parts to create their skeletons, which works out to be 2.8 dKH for every 20 ppm of calcium.
Low alkalinity can be one of the factors of nuisance algae growth. Both low and high alkalinity levels can cause precipitation of calcium. Low alkalinity causes precipitation in the water, while high alkalinity causes precipitation on heat sources like heaters and powerhead impellers.
When you dose alkalinity you will notice that it affects your calcium level by slightly decreasing it. When alkalinity is allowed to fall you will notice that your calcium will rise slightly in comparison causing an imbalance. Alkalinity will be the most challenging to keep consistent. Check it often, and dose as required; this will also help to keep your pH steady. To match the calcium level of 410-420 ppm I like to keep in my tank, I like to keep my alkalinity at about 7-8 dKH.
Balanced Calcium and Alkalinity: (as per Randy Holmes-Farley)
360 ppm to 0 dKH
370 ppm to 1.4 dKH
380 ppm to 2.8 dKH
390 ppm to 4.2 dKH
400 ppm to 5.6 dKH
410 ppm to 7 dKH (natural seawater)
420 ppm to 8.4 dKH
430 ppm to 9.8 dKH
440 ppm to 11.2 dKH
450 ppm to 12.6 dKH
460 ppm to 14 dKH
The relationship between calcium and alkalinity is an important one, and the numbers need to be balanced for optimal absorption by the corals and other life much like the human body needs a balance between calcium and phosphorus to make good bones. Some people may experiment with elevating the alkalinity level beyond the balanced ratio to try to increase coral growth, but there is no proof of this theory. Keep an eye on your calcium level though if you experiment like this as it may decrease your calcium, and may make it difficult to keep your calcium at an acceptable level. Also keep an eye on the precipitation on heat sources as this becomes a waste of your calcium and alkalinity dosing efforts. My aquarium’s alkalinity shot up to 18 dKH at one time, and at this point some corals did show irritation, but nothing was lost.